Uh&#39; 3 &#39;cermet

ABSTRACT

UH3-Ductile metal cermet is used as a radiation shield in a shipping cask for spent nuclear fuel rods.

United States Patent Kasberg June 10, 1975 Ul-l CERMET [56] References Cited [75] inventor: Alvin H. Kasberg, Murrysville, Pa. UNITED STATES PATENTS [73] Assignee: Atlantic Richfield Company, 2,877,088 3/1959 Wellborn et a1 423/255 Philadelphia, Pa. 7 Primary Examiner-Stephen C. Bentley [22] 1973 Attorney, Agent, or Firm-John R. Ewbank [21] Appl. No.: 402,934

lRelated US. Application Data [57] ABSTRACT [62] Division of Ser. No, 160,498, J l 7 1971 p Ull -Ductile metal cermet is used as a radiation shield 3,781,189. in a shipping cask for spent nuclear fuel rods.

[52] US. Cl 252/478; 29/ 182.5 5 Claims, No Drawings [51] int. Cl C04b 35/50 8] Field of Search 29/1825; l76/DIG. 2; 250/507, 515, 517, 518; 252/478; 264/.5; 423/255 UH CERMET This is a divisional of application Ser. No. 160,498 filed July 7. I971, now US. Pat. No. 3,781,189.

BACKGROUND OF THE INVENTION 1. Field of the Invention This invention relates to a shield material for combined gamma and neutron radiation. More particularly, this invention relates to a material suitable for safe containment of spent nuclear fuel rods. This invention further relates to shipping containers for spent nuclear fuel rods .and a method for their manufacture.

2. Description of the Prior Art Spent nuclear fuel rods contain fission products which include certain isotopes which emit both gamma and neutron radiation. When these fuel rods are to be shipped from their point of use to a distant reprocessing center, safety requires that they be shipped in a shielded container. Depleted uranium together with water contained inside and employed for its hydrogen values have been suggested as shielding materials. E. Blasch et al. THE USE OF URANIUM AS A SHIELD- ING MATERIAL, NUCLEAR ENGINEERING AND DESIGN I3 (1970), pages 146-182. Designs such as these necessarily involve very heavy casks and create a transportation problem since, even with specially designed trucks, the shipping casks plus truck are heavier than the capacity of existing roadways. A further problem with this app oach is that of containing the water since a water-tight container must be maintained. Furthermore, the water can become contaminated and may be released accidentally. An alternative approach is to add hydrogen-containing material on the outside of the depleted uranium or lead container such as plastic, however, such materials also add significantly to the cask weight.

While uranium hydride has been suggested as a material for combined neutron and gamma shielding, (e.g., Gibb, .lr., HYDRIDE AND METAL-HYDROGEN SYSTEMS, NEPA-l84l, US. Atomic Energy Technical Information Service, Apr. 30, 1951) no practical way has ever been suggested to apply this theoretical concept. As UH has only heretofore been available in powder form which is highly unstable and violently reactive upon exposure to atmosphere or moisture, it has not been seriously considered for this use. No one has conceived of a practical method for utilization of the properties of uranium hydride in an efficient neutron and gamma shield situation. Furthermore, no one has conceived of a method for incorporating uranium hydride in a spent nuclear fuel rod shipping cask.

SUMMARY OF THE INVENTION It is therefore an object of this invention to provide a method for transporting spent radioactive fuel containing fission products which are a high energy neutron source. It is a further object to provide a method for manufacturing a combined gamma and neutron radiation shield for a shipping cask or the like. A still further object is to provide a shield composition which has greater neutron shielding per unit weight than any previously recognized shield material, most especially, one which may be used for high-gamma shielding purposes as well. It is a still further object to provide a cask for spent nuclear fuel rods which is comparatively light, has high neutron and gamma shielding properties, and

has improved thermal conductivity for removing the heat from the cask contents. These and other objects, as will become apparent from the following description, are achieved by the use of a cermet composition comprising a compacted blend of UH powder and powder of a metal selected from the group consisting of copper, aluminum, lead and mixtures thereof.

DETAILED DESCRIPTION OF THE INVENTION Description of the Preferred Embodiments The UI-I utilized in this invention contains depleted uranium combined chemically with hydrogen and is a brittle material available in granular or powder form. This material has low thermal conductivity and mechanical properties which make it very impractical for use alone as a shielding material; especially in environments where it would be subject to heat from a radioactive source and to mechanical pressures. The powder utilized in accordance with this invention is preferably less than 200 mesh and most preferably less than 300 mesh. i

The ductile metal which serves as a binding agent and also as a thermal conductor in accordance with this invention is preferably aluminum, copper, lead or mixtures such as a copper-lead mixture having from 20 to 95 wt. percent copper. The most preferred metal is copper.

The particle size of the ductile metal powder is preferably less than 200 mesh and most preferably less than 300 mesh, that is to say approximately the same size as the UI-I particles utilized.

In one embodiment of this invention the copper or other metal is precoated with a lubricant such as zinc stearate or molybdenum disulfide before it is blended with uranium hydride powder.

The uranium hydride and ductile metal powders are blended thoroughly under an inert atmosphere, that is, one that is oxygen and moisture free. Suitable atmospheres include inert gases such as argon and neon as well as an atmosphere of nitrogen.

The blend preferably contains a volume percent of UH in the range of about 60 to percent by volume. A mechanical compaction is made without heating by any suitable compacting method. The compacting step, of course, takes place under an inert atmosphere. The compacting is done under a pressure of about 30 to 50 tons per square inch, although pressures as low as perhaps 20 tons per square inch'should be suitable.

The final UH density is most suitably above 7.2 grams per cc, with it preferred to be above 7.6 and most preferred to be about 9.5 grams per cc or higher.

An alternate to the cold press compacting embodiment is one in which the cermet is subsequently sintered.

The resulting cermet has mechanical properties and thermal conductivity which make it suitable for use as a shield in a shipping cask for spent nuclear fuel.

One suitable method for fabricating a shipping cask is to contain the cermet referred to above between two structural metal layers. Suitable structural metals include stainless steel.

The structural containment must be made leak tight and provision made for subsequent leak tests, as is the same as with shields comprising uranium metal above.

The following example is presented to illustrate one embodiment of the invention but is not intended to be limiting.

EXAMPLE A blend of 80 volume per cent UH powder of about 300 mesh and 20 volume per cent copper powder of about 300 mesh by mixing intimately under an inert atmosphere of argon in an isostatic bag and then compacting to a UH density of 7.66 grams per cc. It is esti mated that a 2 /2 inch thick brick at this UB density combined with 3 /2 inches of uranium metal has equiva lent shielding capacity to 4% inches of uranium metal combined with 2 inches of hydrogeneous plastic.

The radiation shield materials of the invention are especially suitable for environments where high neutron and gamma shielding per unit weight is required in combination with high heat transfer from the heat producing radioactive material. A shipping cask can be fabricated from this material in much lighter designs for the equivalent neutron and gamma shielding requirement.

Various modifications, alternatives, and improvements should readily become apparent to those skilled in the art without departing from the spirit and scope of the invention.

We claim:

1. A cermet composition comprising a compacted blend of UH powder and powder of a metal from the group consisting of copper, aluminum, lead and mixtures thereof useful for shielding gamma and neutron radiation.

2. The composition of claim 1 wherein the volume per cent of UH is from about 60 to 80.

3. The composition of claim 1 wherein said metal is a mixture of from about 95 to about weight per cent copper and from about 5 to about 20 weight per cent lead.

4-. The composition of claim ll wherein said metal is copper precoated with a lubricant selected from the group consisting of zinc stearate and molybdenum disulfide.

5. A composition comprising a compacted blend of from about 60 to 80 volume per cent UH powder, and the remainder a mixture of copper and lead in a weight ratio of copper to lead from about :5 to 80:20, said mixture having been precoated with a lubricant selected from the group consisting of zinc stearate and molybdenum disulfide, said UH powder having a density of from about 7.6 to about 9.5 grams per cubic cen- 

1. A CERMET COMPOSITION COMPRISING A COMPACTED BLEND OF UH3 POWDER AND POWDER OF A METAL FROM THE GROUP CONSISTING OF COPPER, ALUMINUM, LEAD AND MIXTURES THEREOF USEFUL FOR SHIELDING GAMMA AND NEUTRON RADIATION.
 2. The composition of claim 1 wherein the volume per cent of UH3 is from about 60 to
 80. 3. The composition of claim 1 wherein said metal is a mixture of from about 95 to about 80 weight per cent copper and from about 5 to about 20 weight per cent lead.
 4. The composition of claim 1 wherein said metal is copper precoated with a lubricant selected from the group consisting of zinc stearate and molybdenum disulfide.
 5. A composition comprising a compacted blend of from about 60 to 80 volume per cent UH3 powder, and the remainder a mixture of copper and lead in a weight ratio of copper to lead from about 95:5 to 80:20, said mixture having been precoated with a lubricant selected from the group consisting of zinc stearate and molybdenum disulfide, said UH3 powder having a density of from about 7.6 to about 9.5 grams per cubic centimeter. 